DATASHEET
Formulation
Powder
Storage:
Stable for 2 years after receipt when stored at +4°C.
Product Information:
CAS Number: 1033772-47-2
Molecular formula: C16H20ClN3Ni
Molecular weight: 348.5
Purity: >95% (NMR)
Appearance: Grey powder.
Solubility: Soluble in DMSO, THF, 1,4-dioxane, chloroform, dichloromethane, DMA and toluene. Insoluble in alkanes and water.
InChiKey: IRLHVNUEEKJBEL-UHFFFAOYSA-M
SMILES: C[N]1(C)C2=CC=CC=C2N2C3=C(C=CC=C3)[N](C)(C)[Ni]12Cl
Description:
Reagent used as a catalyst for cross-coupling reactions between alkyl halides and carbon nucleophiles. Catalyst for alkyl-alkyl Kumada coupling of secondary alkyl halides, direct alkylation of heterocyclic C-H bonds, Sonogashira coupling of nonactivated alkyl halides, Kumada-Corriu-Tamao coupling of nonactivated alkyl halides with aryl and heteroaryl nucleophiles. Reactant of pincer NN2 ligand leading to selective carbon-carbon bond formation.